![]() ![]() "There is one consolation in being sick and that is the possibility that you may recover to a better state than you were ever in before." - Henry David Thoreau.Listen to the doctors you meet and before you know it, you'll be back on your feet." - C. "There is no medicine like hope, no incentive so great, and no tonic so powerful as expectation of something tomorrow." -Orison Swett Marden."Healing takes courage, and we all have courage, even if we have to dig a little to find it." -Tori Amos.Tip toe if you must, but take a step." -Naeem Callaway "Sometimes, the smallest step in the right direction ends up being the biggest step of your life."We are stronger in the places we have been broken." -Ernest Hemingway.You can't do it all, but you can do your best." -Doe Zantamata Be positive, stay strong, and get enough rest. Look for the blessing instead of the curse. "Some days are better, some days are worse."Resting is not laziness, it's medicine!" -Glenn Schweitzer."Promise me you'll always remember: You're braver than you believe, and stronger than you seem, and smarter than you think." -A. ![]()
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![]() ![]() This analysis suggests also that the naked cation Co 3+ would oxidize chloride to chlorine, precluding the formation of CoCl 3. An authoritative monograph states, "Apart from CoF 3, the only known halides of cobalt are the dihalides." The reduction potential for Co 3+ + e - → Co 2+ is more favorable (+1.92 V) than the reduction Cl 2 to Cl - (+1.36 V). The existence of cobalt(III) chloride, CoCl 3, is disputed, although it is listed in some compendia. The German chemist Alfred Werner was awarded the Nobel prize in 1913 for his studies on a series of these cobalt(III) compounds, work that led to an understanding of the structures of such coordination compounds. Unlike Co(II) complexes, Co(III) complexes are very slow to exchange ligands, so they are said to be kinetically inert. Other highly basic ligands including carbonate, acetylacetonate, and oxalate induce the formation of Co(III) derivatives. The reaction is often performed in the presence of charcoal as a catalyst, or hydrogen peroxide is employed in place of air. For example:Ĥ CoCl 2♶H 2O + 4 Cl + 20 NH 3 + O 2 → 4 Cl 3 + 26 H 2O In the presence of ammonia or amines, cobalt(II) is readily oxidised by atmospheric oxygen to give a variety of cobalt(III) complexes. This 19-electron species is a good reducing agent, being readily oxidised to the yellow 18-electron cobaltacenium cation, which is isoelectronic with ferrocene. Reaction of anhydrous CoCl 2 with sodium cyclopentadienylide in THF gives the black sandwich compound cobaltocene. For example, the reaction of 1-norbonyllithium with CoCl 2 produces the brown, thermally stable cobalt(IV) tetralkyl - the only compound of its kind for which the detailed structure is fully known : In the laboratory, cobalt(II) chloride serves as a standard precursor for the synthesis of other cobalt compounds. Otherwise, aqueous solutions of cobalt(II) chlorides behave like other cobalt(II) salts, such as precipitating CoS upon treatment with H 2S. These cobalt (II) complexes are usually either octahedral or tetrahedral. Similarly, paper impregnated with cobalt chloride, known as "cobalt chloride paper" is used to detect the presence of water.ĬoCl 2♶H 2O and CoCl 2 are weak Lewis acids that convert to many other complexes. When cobalt(II) chloride is added as an indicator, the drying agent is blue when still active, pink when exhausted, corresponding to anhydrous and hydrated CoCl 2, respectively. In the US calcium sulfate is sold as a drying agent under the trade name Drierite. The hydrated form can be prepared from cobalt(II) hydroxide or cobalt(II) carbonate and hydrochloric acid.Ī common use for cobalt(II) chloride was for the detection of moisture, for example in drying agents such as silica gel this use was disscontinued due to the carcenogenic nature of cobalt salts. CoCl 2♶H 2O is deliquescent and the anhydrous salt CoCl 2 is hygroscopic, readily converting to the hydrate.Ĭobalt(II) chloride can be prepared in its anhydrous form from cobalt metal and chlorine gas: It has the interesting property that a concentrated aqueous solution is red at room temperature, but becomes blue when heated. This species dissolves readily in water and alcohol. In the solid state CoCl 2♶H 2O contains trans-♲H 2O, two water molecules in its formula unit being water of crystallization. The rose hexahydrate is one the most common cobalt compounds in the laboratory.Īqueous solutions of both CoCl 2 and the hydrate contain the species 2+. Because of this dramatic color change and the ease of the hydration/dehydration reaction, "cobalt chloride" is used as an indicator for water. CoCl 2 is blue, and CoCl 2♶H 2O is deep rose. ![]() Rhodium(III) chloride Iridium(III) chlorideĮxcept where noted otherwise, data are given for materials in their standard state (at 25 ☌, 100 kPa) Infobox disclaimer and referencesĬobalt(II) chloride is the chemical compound with the formula Co Cl 2, although the term is used also to refer to the hexahydrate, which is a different chemical compound. ![]() 2 Dangerous for the environment ( N)Ĭobalt(II) fluoride Cobalt(II) bromide Cobalt(II) iodide Cobalt(II) oxide ![]() ![]() ![]() Samhain heralded the start of the colder months in the Celtic religion. It’s a tale that has clearly influenced the modern, where pumpkins are carved with scary faces, lit from within with a candle and placed in windows on Halloween night. The old Irish tale of Stingy Jack explains the origin of the Jack-o’-Lantern. Find the perfect jack o lanterns turnips stock photo, image, vector, illustration or 360 image. ![]() She studies bacterial and fungal symbioses with legumes and loves all things fungi! She also runs science outreach events. One the most famed legends associated with this ghostly time is the intriguing tale of Jack O’Lantern. Jack o lanterns turnips hi-res stock photography and images - Alamy Find the perfect jack o lanterns turnips stock photo, image, vector, illustration or 360 image. This enables scientists to understand what is happening at a molecular level just by looking at a cell through a microscope.Ībout the author: Kirsty Jackson is a PhD student at the John Innes Centre, Norwich. Luciferase is commonly used in biology to help identify which genes are switched on and how those genes are regulated. This is the same process as occurs in the tails of fireflies. This is a natural phenomenon known as bioluminescence and arises from the activity of an enzyme called luciferase that acts upon a molecule called luciferin and emits light in the process. In the day the Jack O’lantern mushrooms appear orange in colour but in low light levels can be seen to glow a spooky green around the gills. This mushroom is toxic to humans and is often mistaken for the edible chanterelle ( Cantharellus cibarius). Since turnips are not hollow, it can be difficult to cut a lid that fits precisely on the top. (I find it simpler to make my Turnip-O-Lanterns this way rather than cutting the top off, as you might do with a pumpkin. This cut creates a flat base for your lantern. An Irish myth about a man nicknamed Stingy Jack is believed to have led to the tradition of carving scary faces into gourds. Step 2: With a sharp kitchen knife, cut away the section you decide is the bottom. ![]() Jack O’lantern is also the common name for the mushroom Omphalotus olearius. The original Jack-o-lanterns were carved out of turnips. Images by Thomas Schoch (top image) Noah Siegel (bottom image) via Wikimedia Commons. Jack O’lantern fungi by day and by night. ![]() ![]() The original recipe is from, Spoon Bread Casserole. I have no affiliation with any of the products shared in this post. Stir together the cornbread mix, sour cream, eggs and half of the cheese in a bowl. Serve this side dish at any holiday table or really any day you just want some good ol’ comfort food. Prep is extra fast using Jiffy cornbread mix, creamed corn, and of course, lots of butter. This Corn Casserole recipe is one of our favorite Thanksgiving side dishes. PLEASE NOTE – This is not a sponsored post. This easy dish is a perfect holiday side, great with ham or turkey. Easy Oven Roasted Green Beans with Mushrooms.Skillet Maple Glazed Carrots with Pecans.Best-Ever Brussels Sprouts (with Maple & Bacon). ![]() Looking for more great side dishes? Be sure to check out these recipes: Want to make the casserole from scratch? Head over to Classy Cooking and check out a great from scratch recipe. Check out this Egg-Free version from Tastes of Lizzy T. The casserole may take longer to bake, so be sure to keep an eye on it.Ĭan Corn Casserole be made without eggs? Yes, you can omit the eggs, but as a result the casserole won’t be as cakey. It’s also a great side for Mexican dishes like, Queso Chicken Tacos and Easy Cheesy Beef Enchiladas.Ĭan you double the recipe? Yes! Simply double the ingredients and bake at the same temperature in a 9×13 baking dish. ![]() G reat served with roasted chicken, honey baked ham, Thanksgiving turkey. What can be served with Corn Casserole? This makes a great side for so many meals. Corn Casserole Frequently Asked Questions: *Be sure to adjust baking times according to your oven. The casserole is ready when the center is set and the top starts to turn a light golden brown. Bake on middle rack of oven for 40-45 minutes. Last, pour the batter in prepared baking dish. Cover with plastic wrap and refrigerate up to 2 days. After that, add the Jiffy Corn Muffin Mix and blend until thoroughly mixed. Make Ahead - To make ahead, baked as directed and cool completely. Next, add the corn (cream style corn and whole corn – be sure to drain whole kernel corn), mix well.Īdd the eggs and mix well. In a large bowl add sour cream and melted butter, mix until well blended. In a small bowl, beat eggs and set aside. and spray an 8×8 baking pan (or 1 1/2 quart baking pan) with non-stick cooking spray. Step Two Stir to combine everything well.
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Click ‘Customise Cookies’ to decline these cookies, make more detailed choices, or learn more. ![]() Third parties use cookies for their purposes of displaying and measuring personalised ads, generating audience insights, and developing and improving products. Let’s discover what makes this tee special now Huge collection Dinosaur Claw Grabber of men’s tshirts at low offer price & discounts, Easy Returns & Exchanges. This includes using first- and third-party cookies, which store or access standard device information such as a unique identifier. Dinosaur Claw Grabber is a hot-selling item that draws a lot of attention. DINOBROS Dinosaur Chomper Toys for Kids with 3 Roar Sounds and Light Jurassic Dinosaurs Grabber Claw T-Rex Snapper Fun Robot Hand Pincher Dino Game Visit the DINOBROS Store 4.3 73 ratings Amazon's Choice for 'dinosaur grabber' Prime Day Deal -38 999 Typical price: 15. If you agree, we’ll also use cookies to complement your shopping experience across the Amazon stores as described in our Cookie Notice. We also use these cookies to understand how customers use our services (for example, by measuring site visits) so we can make improvements. We use cookies and similar tools that are necessary to enable you to make purchases, to enhance your shopping experiences and to provide our services, as detailed in our Cookie Notice. Dinosaur Claw Grabber Health Pickup & shipping Sort by Dinosaur Claw Grabber (1000+) Pickup & shipping Price Brand Departments Speed Special Offers Rating Color Material Gender Lifestage Condition Size Product Category Category Foldable Retailer 1 2 3. ![]() ![]() “I remember going with my Mawmaw Merriman to get her hair and nails done at the barber shop which is still open in downtown Plano. Of course, back then, all stores were closed on Sundays, so this was possibly a time they shopped. I don’t remember if shops were open or not however, at that time, there were two drug stores, two grocery stores and a restaurant that I think were open. Many people from Plano would gather to talk and visit. ![]() “When my sister, Judy, and I would spend the night with Grandma and Grandpa Turner on Saturday nights, they always went to downtown Plano. It opened at mid-term of my senior year.” Dairy Queen grand opening // courtesy JPlano Star-Courier “I graduated from Plano High School in 1962 in the first class to graduate from the new high school, now known as T.H. All grades of school were in the same building, known now as The Cox Building. ![]() I could drive all the way to school on dirt roads. “I lived 11 miles from Plano in the country, which is now at the corner of Windhaven and the Dallas North Tollway. It was so simple, but at the time we were happy and didn’t know any differently. That really only included going to the Dairy Queen, around a couple of blocks and back to the Dairy Queen to see who was out doing the same thing we were. “At night, especially in the summer, all there was to do was ride around town. Plano High School football team in the 1953 “Planonian” yearbook The Cox Building in the background was the high school at the time // courtesy Genealogy Center of Plano Public Library ![]() It was about 440 yards around the oval, so that was where we practiced. Our track was an oval white rock road that circled the football field and stadium seats. Back in those days, we never got water-only ice. Half an orange and a very small cup of honey was our halftime treat. It was hot the first of the season and cold near the end. I can remember halftime talks in the three-sided bus barn with a gravel floor. The football and track teams would walk to Rice Field from the school house. “Most of my memories are from high school. Fun times!” The Happy Time Kindergarten float in the Christmas parade in downtown Plano note the Masonic Lodge in the background // courtesy Kemper Smith We would go to The Hamburger Place to visit, play the juke box and dance. We would chip in a dime, nickel or quarter to fill up our friend’s car. The children would dress like Pilgrims and Indians. To celebrate Thanksgiving, they always had a Thanksgiving dinner. They taught only five year olds for half a day. The school was called Happy Time Kindergarten. Athello Walker established the first kindergarten in Plano. She would set up a party line for us to talk to each other and make our plans for the day. Our friend, Carol, worked one summer as the phone operator. If we couldn’t find our moms, we would call her and she could usually find them. She knew everybody and everything happening in Plano. There was a phone system where you gave a phone number, and she would connect you to that number. “Althra Philpott was the switchboard operator at the phone company. We would decide which character in the movie we wanted to play, then we would act out the movie. After the movie, we would go to someone’s house. You could buy a movie ticket, popcorn and a Holiday Sucker for about $1. We would go to the movie on Saturday afternoon. If you own a home or a business in Plano Collin County and you need Plano Roller Rink, then give Thunderbird Roller Rink a call now or fill out the contact form below and someone will get back to you and help you with your Plano residential, commercial, or industrial needs.“It was fun living in Plano. Please reach out to us today so Thunderbird Roller Rink can help you solve any questions you have to meet your goals as a local consumer. Inquire about Plano Skate Rink and call Thunderbird Roller Rink today! Plano Roller Rink Thunderbird Roller Rink in Collin County TX, 75075įind a Plano Roller Rink that is here to serve you. We are always happy to provide you with quality Plano Skate Rink and excellent customer service. If you need Skate Rink services, then call us now at (972) 422-4447. Feel free to fill out our contact form here at the bottom of our profile on so we can reach out to you! Thunderbird Roller Rink is a local Plano Skate Rink area business. ![]() Our business community thrives when each of us researches locally first for Skating Rinks Plano and then makes an honest effort to do business with them.Ĭall a Plano Skating Rinks today! Plano Skate Rink Talk directly with the Skating Rinks experts or a business owner on each call. 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Disney Store Official Angel Medium Soft Plush Toy, Lilo and Stitch, 38cm/14, Cuddly Character Made with Soft-Feel Fabric and Embroidered Features, Suitable for All Ages. ![]() ![]() ![]() "I touched him, and I told him I was sorry." "I stabbed him … and he looked up at me like, 'Why'd you do that, mom?'" Herold said. Herold had said she gave the chimp the anti-anxiety drug Xanax, but later retracted that statement.Įven though Travis had lived with Herold for 14 years, and she had called the pet her son, she put her friend first. He became agitated because he wasn't allowed to go for a car ride. On the day of the attack, Travis had eaten a meal of fish and chips and Carvel ice cream. The chimpanzee was sometimes taken out of his room-size cage to eat meals sitting at the dinner table with Herold, and occasionally drank wine from a wineglass. He reportedly enjoyed surfing the Internet and could change the channels on the television using a remote control. The 15-year-old chimp, killed by cops, had starred in an Old Navy television commercial advertising cargo shorts. Nash said the chimp was usually kept in a cage, and when it had been allowed outside as a baby, years earlier, he had ripped the hair from her scalp, causing her to tear up and Herold to laugh at the incident. If she had to rush out or couldn't come home, I fed him," Nash said. "It was her pet that she wanted for a companion. Travis, she said, was Herold's pet and not part of Desire Me Motors, the towing company Herold ran out of her home. "I do remember going to feed him a couple of times," she said. Nash told Winfrey that taking care of the ape was not part of her job, and she was frightened to even be around the animal. The chimp's owner claims that Nash was her employee at the time of the attack and is entitled to file only a workmen's compensation claim, which would greatly limit the amount of money she could receive. Nash has filed a civil suit against Herold, seeking $50 million in damages for pain and suffering. I want to be independent, but I don't want to be alone anymore." "Before, I was always really independent," she said. She said she hopes to one day be out of the hospital and more independent. And sometimes other people might insult you." Nash said she wears the veil "so I don't scare people. When outside her hospital room, she wears a hat and veil, usually made from a handkerchief attached to the brim of a straw hat. I hope she has a good time there," Nash said. "Her prom is coming up, and I can't pick out a gown, so I really hope she picks out something appropriate to wear. ![]() Among her few regrets is the inability to help her daughter pick out a prom dress. I miss her too."Īmong the moments she relishes is her daughter crawling in bed with her, and they hold each other. "I'm sorry I can't spend more time with my daughter," Nash said. Nash goes for daily walks around the hospital and relishes the occasional visits she shares with her 17-year-old daughter, Brianna. The dispatcher later asked, "Who's killing your friend?" ![]() ![]() ![]() QuickTime video support, Menus available when no documents are open, Import images from scanners and cameras Introduced an icon set with designs that more closely resemble typical Mac OS X icons than those of. Moreover, the whole application is free of charge.Ī timeline of major derivatives of StarOffice and with NeoOffice in light purple OOo version This has changed in 2022 as the code and all commits are released on GitHub. As of 2016, the source code is still available for free, but the software package was only available with the purchase of a commercial license. In 2013, NeoOffice moved to a commercial distribution model via the Mac App Store. NeoOffice 2017 and later versions are fully based on LibreOffice. Many of these releases were preceded by a version that only Early Access Members could download these versions were released about a month before the official release date.Īll versions from NeoOffice 3.1.1 to NeoOffice 2015 were based on 3.1.1, though latter versions included stability fixes from LibreOffice and Apache OpenOffice. The "/J" suffix was dropped with version 1.2, since there was no longer another variety of NeoOffice from which to distinguish it. But NeoOffice/C proved very difficult to implement and the application was highly unstable, so the project was set aside in favor of the more promising NeoOffice/J. A related project was NeoOffice/C, which was a simultaneous effort to develop a version using Apple's Cocoa APIs. The project now called NeoOffice was originally dubbed "NeoOffice/J", reflecting its use of Mac OS X's Java integration to enable a native application. NeoOffice began as a project to investigate methods of creating a native port of to Mac OS X. Subsequently, both LibreOffice and Apache OpenOffice followed NeoOffice's lead and implemented similarly native Mac OS X interfaces. NeoOffice was the first fork to offer a native Mac OS X experience, with easier installation, better integration into the Mac OS X interface (pull-down menus at the top of the screen and familiar keyboard shortcuts, for example), use of Mac OS X's fonts and printing services without additional configuration, and integration with the Mac OS X clipboard and drag-and-drop functions. Versions of for Mac prior to 3.0 did not have a native Mac OS X interface they required that either X11.app or XDarwin be installed. Current versions are based on LibreOffice 4.4, which was released mid-2014. It is a commercial fork of the free and open source LibreOffice office suite, including a word processor, spreadsheet, presentation program and graphics program, it adds some features not present in the macOS versions of LibreOffice and Apache OpenOffice. NeoOffice is an office suite for the macOS operating system developed by Planamesa Inc. ![]() |
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